I want to configure DD4T 2.0 alongside Tridion 2013 SP1, wondering if it could be configured with MVC 3 and VS 2010 as I am not able to find any document reference to this. Please help with any guide to it.
These are very old versions and no longer supported by MS as also mentioned by Rob in comments. so not recommended. But as your asked my observations are as follow.
I checked DD4T 2.0.0 beta source code (which i have on my machine). Up-to this version
System.Web.Mvc 3.0 is used and target .net framework 4.0 , then i think it matches your requirements.
but DD4T version
2.0.7 or later requires MVC4 or MVC 5.
My personal view, you can do some homework, download open-source code and target using your required framework and resolve any error (i don't expect much errors/warnings as up-to major version 2.0 is using mvc 3.0 and .net 4)